Maillard reaction

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Maillard Reaction

The Maillard Reaction (pronounced: my-YAR ree-AK-shun) is a chemical reaction between amino acids and reducing sugars that gives browned food its distinctive flavor.

Etymology

The term "Maillard Reaction" is named after the French chemist Louis-Camille Maillard, who first described it in 1912 while attempting to reproduce biological protein synthesis.

Definition

The Maillard Reaction is a form of non-enzymatic browning which typically proceeds rapidly from around 140 to 165 °C (280 to 330 °F). At higher temperatures, caramelization and subsequently pyrolysis become more pronounced. The reactive carbonyl group of the sugar reacts with the nucleophilic amino group of the amino acid, and forms a complex mixture of poorly characterized molecules responsible for a range of odors and flavors. This process is accelerated in an alkaline environment (e.g., lye applied to darken pretzels), as the amino groups (RNH3+) are deprotonated and, hence, have an increased nucleophilicity.

Related Terms

  • Amino Acids: Organic compounds that combine to form proteins. Amino acids and proteins are fundamental components of all living cells.
  • Reducing Sugars: Any sugar that is capable of acting as a reducing agent because it has a free aldehyde group or a free ketone group.
  • Caramelization: The browning of sugar, a process used extensively in cooking for the resulting sweet nutty flavor and brown color.
  • Pyrolysis: The thermal decomposition of materials at elevated temperatures in an inert atmosphere.

See Also

External links

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