Diphenylchlorarsine

Diphenylchlorarsine

Structure of Diphenylchlorarsine

Diphenylchlorarsine is a chemical compound that belongs to the class of organoarsenic compounds. It is also known by its chemical formula C12H9AsCl. Diphenylchlorarsine is a yellowish crystalline solid that is primarily used as a chemical warfare agent due to its toxic properties. It was first synthesized in the early 20th century and has since been used in various military applications.

History

Diphenylchlorarsine was first synthesized in 1918 by German chemists during World War I. It was initially developed as a potential chemical weapon due to its ability to cause severe irritation and incapacitate enemy soldiers. However, its use as a weapon was limited during the war, and it was not until later conflicts that its full potential as a chemical warfare agent was realized.

Properties

Diphenylchlorarsine is a solid compound with a molecular weight of 274.5 g/mol. It has a melting point of approximately 80°C and a boiling point of around 300°C. The compound is insoluble in water but soluble in organic solvents such as benzene and chloroform. It has a characteristic odor similar to that of garlic.

Toxicity

Diphenylchlorarsine is highly toxic and can cause severe health effects upon exposure. It primarily affects the respiratory system, causing irritation of the lungs and airways. Inhalation of the compound can lead to symptoms such as coughing, chest pain, and difficulty breathing. Prolonged exposure or high concentrations can result in more severe respiratory distress and even respiratory failure.

Uses

Diphenylchlorarsine has primarily been used as a chemical warfare agent. It is classified as a vomiting agent, as it induces nausea and vomiting in exposed individuals. This effect can be debilitating, incapacitating soldiers and rendering them unable to continue fighting. The compound has also been used in riot control situations, where its irritant properties are utilized to disperse crowds.

Safety Precautions

Due to its toxic nature, handling and storage of diphenylchlorarsine should be done with extreme caution. Protective clothing, including gloves and respiratory protection, should be worn when working with the compound. Proper ventilation is necessary to prevent the buildup of toxic fumes. In case of exposure, immediate medical attention should be sought, and affected individuals should be removed from the contaminated area.

See Also

• Chemical warfare agents
• Organoarsenic compounds