Molecular geometry

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Molecular Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms in a molecule. It is a fundamental aspect in the study of chemistry, particularly in the areas of molecular biology, biochemistry, and medicinal chemistry.

Pronunciation

Molecular Geometry: /məˈlɛkjʊlər ˈdʒiːəmɪtri/

Etymology

The term "molecular" is derived from the Latin word "molecula", which means "small mass". "Geometry" comes from the Ancient Greek words "geo-" meaning "earth", and "-metron" meaning "measurement".

Definition

Molecular geometry is used to describe the shape of a molecule, the angles between its bonds, and the way its atoms are arranged in space. It is determined by the number of bonding and non-bonding electron pairs in the molecule's valence shell.

Related Terms

  • Bond angle: The angle formed between three atoms across at least two bonds.
  • Steric number: The total number of atoms bonded to a central atom of a molecule plus the number of lone pairs of electrons.
  • VSEPR Theory: A model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms.
  • Hybridization: The concept of mixing atomic orbitals into new hybrid orbitals.

Molecular Geometry Types

There are several types of molecular geometries, including linear, trigonal planar, tetrahedral, trigonal bipyramidal, and octahedral. Each of these geometries is associated with a specific steric number and set of bond angles.

  • Linear: This geometry has a steric number of 2 and bond angles of 180°.
  • Trigonal Planar: This geometry has a steric number of 3 and bond angles of 120°.
  • Tetrahedral: This geometry has a steric number of 4 and bond angles of 109.5°.
  • Trigonal Bipyramidal: This geometry has a steric number of 5 and bond angles of 90° and 120°.
  • Octahedral: This geometry has a steric number of 6 and bond angles of 90°.

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