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What is 14-Hydroxydihydrocodeine?

  • It is an opiate analgesic and an active metabolite of oxycodone and hydromorphinol[1].
  • IUPAC Name: 9-methoxy-3-methyl-1,2,4,5,6,7,7a,13-octahydro-4,12-methanobenzofuro[3,2-e]isoquinoline-4a,7-diol
  • InChI: InChI=1S/C18H23NO4/c1-19-8-7-17-14-10-3-4-12(22-2)15(14)23-16(17)11(20)5-6-18(17,21)13(19)9-10/h3-4,11,13,16,20-21H,5-9H2,1-2H3
  • Canonical SMILES: CN1CCC23C4C(CCC2(C1CC5=C3C(=C(C=C5)OC)O4)O)O
  • Molecular formula: C18H23NO4
  • Molecular weight: 317.4 g·mol−1
  • Synonyms:
  1. SCHEMBL6097780



  1. Ishida T, Oguri K, Yoshimura H (1979). "Isolation and identification of urinary metabolites of oxycodone in rabbits". Drug Metabolism and Disposition. 7 (3): 162–5 [1].
  2. National Center for Biotechnology Information (2021). PubChem Compound Summary for CID 14368119, 14-Hydroxydihydrocodeine. Retrieved August 3, 2021 from [2].

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