Aluminium monofluoride

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Aluminium Monofluoride

3D model of Aluminium Monofluoride

Aluminium monofluoride (AlF) is a chemical compound consisting of aluminium and fluorine. It is a diatomic molecule that is of interest in various fields of chemistry and materials science.

Structure and Properties

Aluminium monofluoride is a gaseous compound under standard conditions. It is known for its linear molecular geometry, which is typical for diatomic molecules. The bond between the aluminium and fluorine atoms is polar covalent, with fluorine being more electronegative than aluminium, resulting in a dipole moment.

The compound is often studied in the context of high-temperature chemistry and is known to form in the gas phase during the reaction of aluminium with fluorine-containing compounds.

Synthesis

Aluminium monofluoride can be synthesized through the direct combination of aluminium and fluorine gases at high temperatures. This reaction is highly exothermic and must be controlled to prevent the formation of other aluminium fluoride species, such as aluminium trifluoride.

Applications

While aluminium monofluoride itself is not widely used in industrial applications, it is of interest in the study of chemical bonding and molecular interactions. Its properties are studied using spectroscopic methods, such as infrared and microwave spectroscopy, to understand the nature of the Al-F bond.

Related Compounds

Aluminium monofluoride is related to other aluminium halides, such as aluminium chloride (AlCl3) and aluminium bromide (AlBr3). These compounds share similar properties and are often studied together to understand the effects of different halogens on the properties of aluminium compounds.

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Contributors: Prab R. Tumpati, MD