Mercury(II) acetate

Mercury(II) acetate is a chemical compound with the formula C4H6O4Hg. It is a white crystalline solid that is soluble in water and organic solvents. Mercury(II) acetate is used primarily as a reagent in organic chemistry for the introduction of mercury into organic compounds and as a catalyst in reactions such as hydration and dehydrogenation. Due to its toxicity and potential environmental impact, its use is subject to strict regulations.

Properties

Mercury(II) acetate has a molar mass of 318.70 g/mol. It has a melting point of 178 °C and decomposes upon heating above this temperature. In solution, it hydrolyzes to give acetic acid and mercuric oxide, indicating its instability in aqueous environments.

Synthesis

Mercury(II) acetate is typically synthesized by reacting mercury(II) oxide or mercury(II) chloride with acetic acid. The reaction involves the dissolution of mercury oxide in hot acetic acid, followed by crystallization of the mercury(II) acetate product.

Applications

In organic chemistry, mercury(II) acetate is used as a reagent in the mercuration of alkenes and alkynes, a process that introduces a mercury acetate group into the molecule. This is often a step towards further functionalization of the organic molecule, such as through demercuration reactions that replace the mercury with other groups.

Safety and Environmental Concerns

Mercury(II) acetate is highly toxic, with exposure routes including inhalation, ingestion, and skin contact. It can cause severe mercury poisoning, leading to kidney damage, respiratory failure, and death. Due to its mercury content, it poses significant environmental risks, particularly to aquatic ecosystems where it can be transformed into methylmercury, a potent neurotoxin. Handling of mercury(II) acetate requires strict safety precautions, including the use of appropriate personal protective equipment and fume hoods.

Regulation

The use and disposal of mercury(II) acetate are regulated under various international and national laws aimed at protecting human health and the environment. These regulations include restrictions on its use, requirements for safe handling and disposal, and measures to prevent its release into the environment.

See Also

• Mercury poisoning
• Organomercury compound
• Acetic acid

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Mercury(II) acetate

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  Ball-and-stick model of Mercury(II) acetate crystal structure

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  Space-filling model of Mercury(II) acetate crystal structure