Nickel(II) chloride

Nickel(II) chloride is an inorganic compound with the formula NiCl₂. This yellowish-green solid is a salt that is highly soluble in water and other polar solvents. It is an important source of nickel for chemical synthesis. Nickel(II) chloride, in various forms, is the most important source of nickel for many chemical reactions, especially in the production of catalysts, pigments, and metal plating solutions.

Properties

Nickel(II) chloride exists in two forms: the anhydrous salt and hydrated forms. The anhydrous form is yellowish-brown and absorbs moisture from the air, converting to the hydrate. The most common hydrate is the hexahydrate, NiCl₂•6H₂O, which is green in color. This compound is deliquescent, absorbing moisture from the air to form a solution.

Chemical

Nickel(II) chloride is a typical ionic compound, with nickel in the +2 oxidation state. It is soluble in water, forming a green solution due to the hydration of the nickel(II) ion. In aqueous solution, it can undergo a variety of reactions, serving as a source of Ni²⁺ for the synthesis of other nickel compounds.

Production

Nickel(II) chloride is produced by the dissolution of nickel or its oxides in hydrochloric acid. It can also be generated by the reaction of nickel with chlorine gas. The hexahydrate form is obtained by crystallization from water.

Applications

Nickel(II) chloride is extensively used in electroplating, providing a source of nickel ions for the deposition of nickel metal onto surfaces. It is also a common starting material in organonickel chemistry, where it serves as a precursor to nickel catalysts used in organic synthesis. Additionally, it is used in the manufacture of colored glasses and ceramics, as well as in the preparation of other nickel salts.

Safety

Nickel(II) chloride is classified as a hazardous substance. It is toxic if ingested, inhaled, or upon contact with the skin. Nickel compounds are known to be carcinogenic and can cause allergic reactions in some individuals. Proper safety precautions, including the use of personal protective equipment, are essential when handling this compound.

Environmental Impact

The use and disposal of nickel(II) chloride must be managed carefully to prevent environmental contamination. Nickel compounds can be toxic to aquatic life and may accumulate in the environment, leading to potential ecological damage.

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Nickel(II) chloride

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  Color of various Ni(II) complexes in aqueous solution

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  Dienol isomerisation 2D skeletal

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  Nickel(II) chloride