Ruthenium(IV) oxide

Ruthenium(IV) oxide is a chemical compound with the formula RuO2. This solid material is the most common oxide of ruthenium. It is widely used in electrochemistry, as a catalyst, and for thin film resistors. Despite its practical importance, ruthenium(IV) oxide is notable for its interesting electrical conductivity and catalytic properties.

Properties

Ruthenium(IV) oxide is a black solid that crystallizes in the rutile structure. It exhibits metallic-like conductivity and is used in various electrochemical applications due to its excellent catalytic properties, especially in the chlorine production and in electrolysis cells. RuO2 is also used as a catalyst in the chemical industry for the production of ammonia and in various other hydrogenation and oxidation reactions.

Synthesis

RuO2 can be prepared by several methods, including the oxidation of ruthenium metal or ruthenium(III) chloride. One common approach involves the controlled heating of ruthenium in the presence of oxygen, which yields ruthenium(IV) oxide directly. Another method is the hydrolysis of ruthenium compounds, followed by thermal decomposition of the hydroxide to RuO2.

Applications

1. 1. 1. Electrochemistry

Ruthenium(IV) oxide is widely used in electrochemical applications, particularly in electrodes for capacitors and chlorine production. Its high conductivity and stability in harsh conditions make it an ideal material for these purposes.

1. 1. 1. Catalysis

As a catalyst, RuO2 is used in a variety of chemical reactions, including the hydrogenation of organic compounds and the oxidation of ammonia. Its effectiveness in these roles is attributed to its high surface area and excellent stability under reaction conditions.

1. 1. 1. Thin Film Resistors

RuO2 is also used in the manufacture of thin film resistors, where it is valued for its stability and resistance properties. These resistors are important components in electronic devices, providing precise control over electrical resistance.

Safety

Ruthenium(IV) oxide should be handled with care, as it is a potent oxidizer and can react violently with combustible materials. Proper safety equipment and procedures should be used when working with this compound to prevent exposure and potential health risks.

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  Ruthenium(IV) oxide unit cell 3D vdW