Supercooling

Supercooling, also known as undercooling, is the process of lowering the temperature of a liquid or a gas below its freezing point without it becoming a solid. This phenomenon occurs because the phase transition from liquid to solid requires a nucleation event, such as the introduction of a seed crystal or particle, around which a solid phase can form. In the absence of nucleation sites, a liquid can be cooled below its standard freezing point while remaining in the liquid phase. Supercooling is a common occurrence in nature and has various applications in science and industry.

Mechanism

The mechanism of supercooling involves cooling a liquid below its freezing point without it crystallizing. This process is delicate and requires avoiding any disturbances that could trigger nucleation. The presence of impurities or contact with a surface can provide nucleation sites, which makes achieving supercooling in practice challenging. Pure substances are more easily supercooled than mixtures because mixtures have multiple components that can act as nucleation sites.

Conditions for Supercooling

Several conditions can enhance the likelihood of supercooling:

• Purity of the liquid: The absence of impurities reduces potential nucleation sites.
• Smoothness of the container: A smooth container minimizes the chances of nucleation.
• Slow cooling: Rapid cooling increases the likelihood of nucleation events.

Applications

Supercooling has various applications across different fields:

• In meteorology, supercooled water droplets play a crucial role in the formation of ice in clouds.
• In the food industry, supercooling can be used to preserve the freshness of products by keeping them in a liquid state below their freezing point.
• In cryopreservation, supercooling is a technique used to preserve organs, tissues, and cells at low temperatures without forming ice crystals, which can cause damage.

Challenges

The main challenge in utilizing supercooling is avoiding nucleation, which can spontaneously occur if the liquid is disturbed or if impurities are present. Achieving and maintaining supercooling in a controlled environment is crucial for its practical applications.

See Also

• Freezing point depression
• Nucleation
• Phase transition
• Cryopreservation

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  Supercooling water bottle before shaking

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  Supercooling water bottle after shaking

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  Constitutional supercooling - phase diagram, concentration, and temperature